Which of the following elements is NOT a primary alloying element in stainless steel?

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RRB JE CBT 2 (Mechanical Engineering) ReExam Official Paper (Held On: 04 Jun, 2025)
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  1. Lead
  2. Chromium
  3. Carbon
  4. Nickel

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Option 1 : Lead
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Explanation:

Stainless Steel and Its Alloying Elements

  • Stainless steel is a corrosion-resistant alloy of iron that contains significant amounts of alloying elements to enhance its properties, such as durability, strength, and resistance to oxidation. The primary alloying elements in stainless steel typically include chromium, nickel, and carbon. These elements play critical roles in imparting the unique characteristics of stainless steel, making it suitable for a wide range of applications, including construction, automotive, medical equipment, and kitchen utensils.

Lead

  • Lead is NOT a primary alloying element in stainless steel. This is because lead does not contribute to the corrosion resistance, strength, or durability of stainless steel. In fact, lead is generally avoided in stainless steel due to its toxicity and inability to bond effectively with the alloy matrix. Lead is primarily used in applications requiring lubrication or machining ease, such as in free-cutting steels, but it is not suitable for stainless steel compositions.
  • Stainless steel relies on elements such as chromium and nickel for its corrosion resistance and mechanical properties. Lead does not provide any of these benefits and would compromise the integrity and performance of the alloy. Therefore, it is excluded from the formulation of stainless steel.

Chromium

  • Chromium is the most critical alloying element in stainless steel. It imparts corrosion resistance by forming a thin, stable oxide layer on the surface of the steel, known as the "passive layer." This layer prevents further oxidation and protects the material from rust and environmental damage. Typically, stainless steel contains at least 10.5% chromium to achieve its signature corrosion-resistant properties.

Carbon

  • Carbon is another important element in stainless steel, although its percentage is kept low to prevent carbide precipitation, which can lead to corrosion. In some grades of stainless steel, carbon is intentionally added in controlled amounts to enhance strength and hardness. For example, high-carbon stainless steels are used in applications requiring wear resistance, such as knives and cutting tools.

Nickel

  • Nickel is a key alloying element in austenitic stainless steels. It stabilizes the austenitic crystal structure, which provides excellent toughness and ductility, even at low temperatures. Nickel also enhances corrosion resistance, especially in environments containing acids or chlorides. Common grades of stainless steel, such as 304 and 316, contain significant amounts of nickel.

Additional Information

Stainless steel is classified into several types based on its microstructure:

  • Austenitic Stainless Steel: Contains high chromium and nickel, providing excellent corrosion resistance and ductility.
  • Ferritic Stainless Steel: Contains chromium but little or no nickel, offering good corrosion resistance and magnetic properties.
  • Martensitic Stainless Steel: Contains chromium and higher carbon levels, providing strength and hardness but lower corrosion resistance.
  • Duplex Stainless Steel: A mix of austenitic and ferritic structures, offering a balance of strength and corrosion resistance.
  • Precipitation-Hardening Stainless Steel: Contains alloying elements like aluminum or copper, which enable heat treatment for enhanced strength.
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