Question
Download Solution PDFMaterials in which the dipole moments of adjacent atoms line up in antiparallel fashion are called:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFExplanation:
Materials in which the dipole moments of adjacent atoms line up in antiparallel fashion are called:
Correct Answer: Anti-ferromagnetic Materials
Definition: Anti-ferromagnetic materials are a class of materials in which the magnetic dipole moments of adjacent atoms or ions align in an antiparallel fashion, meaning they point in opposite directions. This alignment leads to a net zero or very small magnetic moment for the material as a whole. Anti-ferromagnetism is a fundamental phenomenon in solid-state physics and is critical for understanding various magnetic and electronic properties of materials.
Working Principle:
Anti-ferromagnetic materials exhibit a unique arrangement of magnetic moments. In these materials:
- Each magnetic dipole moment aligns in opposition to its neighbor, leading to a cancellation of the overall magnetic moment.
- The antiparallel alignment occurs due to quantum mechanical exchange interactions between neighboring atoms.
- At low temperatures, the anti-ferromagnetic order is stable, but above a certain temperature (called the Néel temperature), thermal agitation disrupts the order, and the material transitions into a paramagnetic state.
Properties of Anti-ferromagnetic Materials:
- Magnetic Behavior: Exhibits no net macroscopic magnetization due to the cancellation of opposing dipole moments.
- Néel Temperature: The temperature at which the anti-ferromagnetic order breaks down and the material becomes paramagnetic.
- Susceptibility: Below the Néel temperature, anti-ferromagnetic materials exhibit low magnetic susceptibility.
- Exchange Interaction: The antiparallel alignment arises from exchange interactions, which depend on the distance between atoms and the nature of the bonding.
Applications:
- Used in magnetic storage devices due to their stable magnetic properties.
- Relevant in spintronics, where the manipulation of spin states is crucial for device functionality.
- Important in neutron diffraction studies for determining magnetic structures.
- Utilized in advanced materials research for designing magnets with specific properties.
Examples of Anti-ferromagnetic Materials:
- Iron oxide (FeO)
- Manganese oxide (MnO)
- Nickel oxide (NiO)
- Chromium (Cr)
Correct Option Analysis:
The correct option is:
Option 2: Anti-ferromagnetic materials
This option correctly identifies materials in which the dipole moments of adjacent atoms align in an antiparallel fashion. Such materials exhibit anti-ferromagnetic behavior due to their unique magnetic ordering, which results in a net zero or negligible macroscopic magnetization.
Additional Information
To further understand the analysis, let’s evaluate the other options:
Option 1: Anti-ferrimagnetic materials
This option is incorrect because "anti-ferrimagnetic" is not a recognized term in magnetism. The concept of ferrimagnetism involves partial alignment of dipole moments, resulting in a net magnetization, which differs from the antiparallel alignment in anti-ferromagnetic materials.
Option 3: Anti-paramagnetic materials
This option is incorrect as "anti-paramagnetic" is not a valid term in the field of magnetism. Paramagnetic materials have unpaired electrons that align with an external magnetic field, unlike anti-ferromagnetic materials which exhibit intrinsic antiparallel alignment of dipoles.
Option 4: Anti-supermagnetic materials
This option is incorrect because "anti-supermagnetic" is not a valid term. Superparamagnetism refers to a phenomenon in small magnetic particles where thermal fluctuations overcome magnetic anisotropy, causing the particle's moment to randomly flip direction. It is unrelated to anti-ferromagnetic ordering.
Option 5: No such materials
This option is incorrect as anti-ferromagnetic materials are well-established in physics and materials science. Their unique antiparallel magnetic ordering is a fundamental concept with numerous applications in research and industry.
Conclusion:
Anti-ferromagnetic materials are characterized by the antiparallel alignment of adjacent atomic dipole moments, resulting in a net zero or negligible magnetic moment. This phenomenon is distinct from other types of magnetic behavior such as paramagnetism or ferrimagnetism. The correct identification of anti-ferromagnetic materials is essential for understanding their properties and applications in various technological domains. Despite the misleading nature of the other options, the correct answer accurately captures the concept of anti-ferromagnetic ordering.
Last updated on Jul 15, 2025
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