Which of the following is left in the sodium hydroxide solution after removing the soap?

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  1. Alcohol
  2. Glycerol 
  3. Esters 
  4. Phenol 

Answer (Detailed Solution Below)

Option 2 : Glycerol 
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Detailed Solution

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The correct answer is Glycerol.

Key Points

  • Glycerol is a byproduct formed during the saponification process, which involves the reaction of fats/oils with sodium hydroxide to produce soap.
  • After soap is removed from the sodium hydroxide solution, glycerol remains dissolved in the solution due to its high solubility in water.
  • Glycerol is a trihydroxy alcohol (1,2,3-propanetriol) and is commonly used in pharmaceuticals, cosmetics, and food industries.
  • It is separated from the solution after soap production through purification processes such as distillation or evaporation.
  • Glycerol has hygroscopic properties, meaning it attracts water, which makes it beneficial for moisturizing applications.

Additional Information

  • Saponification:
    • Saponification is the chemical process of soap production by reacting fats or oils with a strong alkali such as sodium hydroxide (NaOH).
    • The reaction produces soap and glycerol as its main products.
    • The fats/oils used are triglycerides, which are broken down into fatty acid salts (soap) and glycerol.
  • Glycerol Applications:
    • Used as a humectant in cosmetics and skin care products.
    • Serves as a sweetener and preservative in food products.
    • Used in pharmaceutical formulations like cough syrups and suppositories.
  • Sodium Hydroxide:
    • Sodium hydroxide (NaOH) is a strong alkali commonly used in soap production.
    • It reacts with triglycerides during saponification to create soap and glycerol.
    • NaOH is also used in various industries, including paper production and water purification.
  • Separation Techniques:
    • Glycerol is separated from soap by processes like distillation or crystallization.
    • Purified glycerol is further refined for commercial use in multiple industries.
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