An oxygen cylinder of volume 30 litre has 18.20 moles of oxygen. After some oxygen is withdrawn from the cylinder, its gauge pressure drops to 11 atmospheric pressure at temperature 27°C. The mass of the oxygen withdrawn from the cylinder is nearly equal to:
[Given, R = \(R = \frac{100}{12} \) J mol⁻¹ K⁻¹, and molecular mass of O₂ = 32, 1 atm pressure = 1.01 × 10⁵ N/m²]

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  1. 0.125 kg
  2. 0.144 kg
  3. 0.116 kg
  4. 0.156 kg

Answer (Detailed Solution Below)

Option 3 : 0.116 kg
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Correct option is: (3) 0.116 kg

Number of moles left

n = PV / RT = (12 × 1.01 × 105 N/m2 × 30 × 10−3 m3) / ((100/12) × 300)

n = (12 × 1.01 × 12) / 10 = 14.54 moles

Moles removed = 18.2 − 14.54

= 3.656 moles

Mass removed = 3.656 × 32 = 116.99 g = 0.116 kg

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