Which of following reaction names is suitable for the below reaction? 

CH3CH2Br + HS- → CH3CH2SH + Br-

This question was previously asked in
DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. SN1 reaction
  2. SN2 reaction
  3. SNi reaction
  4. SNar reaction

Answer (Detailed Solution Below)

Option 2 : SN2 reaction
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Detailed Solution

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CONCEPT:

SN2 Reaction Mechanism

  • SN2 (Substitution Nucleophilic Bimolecular) reactions involve a single step mechanism where the nucleophile attacks the substrate at the same time as the leaving group departs.
  • The reaction follows second-order kinetics, meaning the rate of reaction depends on both the concentration of the nucleophile and the substrate.
  • The nucleophile performs a backside attack, leading to an inversion of the configuration if the substrate is chiral (known as Walden inversion).

EXPLANATION:

  • In the given reaction:

    CH3CH2Br + HS- → CH3CH2SH + Br-

    • The substrate CH3CH2Br undergoes nucleophilic substitution.
    • The nucleophile HS- attacks the carbon atom bonded to the bromine atom (Br) in a backside attack.
    • Bromine (Br) acts as the leaving group and departs simultaneously with the nucleophile attack.
    • This mechanism is consistent with an SN2 reaction, which occurs in one step without the formation of an intermediate.

The reaction mechanism does not involve the formation of a carbocation (as in SN1), nor does it involve intramolecular substitution (SNi) or aromatic substitution (SNar).

Therefore, the correct answer is SN2 reaction.

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