Question
Download Solution PDFThe transition state of SN2 reaction has:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
SN2 Reaction and its Transition State
- SN2 (bimolecular nucleophilic substitution) reactions occur in a single concerted step where the nucleophile attacks the electrophilic carbon and displaces the leaving group simultaneously.
- The transition state of an SN2 reaction is characterized by simultaneous bonding of the nucleophile and leaving group to the central carbon atom.
- In this state, the central carbon atom exhibits a unique structure, often referred to as "pentacoordinate" due to five bonds interacting simultaneously.
EXPLANATION:
- The transition state is not a stable structure but a high-energy intermediate that exists momentarily during the reaction.
- In an SN2 reaction:
- The nucleophile attacks the electrophilic carbon from the opposite side of the leaving group.
- The structure of the transition state is neither tetrahedral nor planar but has a trigonal bipyramidal geometry.
- Thus, the central carbon atom in the transition state does not have a normal tetrahedral structure or square planar geometry.
- The correct description of the transition state is a carbon with a linear structure due to simultaneous attack and departure of groups.
Therefore, the correct answer is Carbon tetrahedral structure.
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